Discover Airlines, owned by the Lufthansa Group, will launch a direct flight between Munich and Windhoek on April 1 next year.
The airline is expanding its long-haul operations from its new base in Munich and will be the only carrier offering a direct service between the cities.
The flight will operate year-round on Tuesdays, Thursdays, and Saturdays from Terminal 2 at Munich Airport.
Until now, the airline has offered only short- and medium-haul services from the airport. In addition to Windhoek, Discover will also launch flights to Orlando, Florida, and Calgary, Canada.